Systematic study of short circuit activation on the performance of PEM fuel cell

During the operation of proton exchange membrane fuel cell (PEMFC), it always suffers from reversible performance loss caused by the oxidation of platinum catalyst on its electrode, which reduces the electrochemical active surface area. Short circuit method has been found to improve the performance of fuel cells by stripping of oxides and other adsorbed species from platinum, which needs systematical understanding the effective parameters of short circuit method on fuel cell performance. In this paper, the effects of different short circuit activation parameters (duration, interval, cycles, cut-off voltage, operating current) are carefully studied and analyzed during short circuit operations. In addition, the mechanism revealing how relevant parameters influence short circuit activations is deeply analyzed. The results show that five groups of activation parameters have obvious influence on the activation of fuel cell, indicating that the short-circuit activation effect can be optimized. Among these parameters, the short-circuit duration parameter have the greatest impact on activation, because the platinum hydroxides and oxides is gradually removed during short-circuit duration and results in a larger effective surface area of the platinum catalyst for the electrochemical reaction. However, the smallest impact is short-circuit interval. Another finding is that the five activation parameters are not independent, so the optimal activation parameter value needs to be analyzed in combination with the operating conditions. Finally, according to the activation principle, selection of appropriate short circuit activation parameters for application are proposed to further improve performance and fuel utilization by considering the safety of the stack.     

Comparison of γ-aminobutyric acid accumulation capability in different mung bean (Vigna radiata L.) varieties under heat and relative humidity treatment,and its correlation with endogenous amino acids and polyamines

In this study, the accumulation of GABA and its inherent factors across different varieties of mung bean (Vigna radiata L.) in response to heat and relative humidity (HRH) were investigated. Results showed the average GABA content in mung bean varieties was increased 7.52 times following HRH treatment, and the black mung bean variety (A8) exhibited the highest GABA accumulation capability (1.76–84.57 mg per 100 g DW). From the perspective of GABA shunt metabolites, the free glutamic acid content of mung beans significantly decreased (P < 0.05) after HRH treatment and presented a significant correlation (P < 0.05) with GABA content. In polyamine degradation pathway, although the average levels of spermine and spermidine of mung bean varieties significantly decreased (P < 0.05) after HRH treatment, no significant correlation with GABA content was identified. Hence, the GABA accumulation was predominantly attributed to GABA shunt. Besides, free amino acids including glutamic acid, serine, ornithine, arginine and glycine in mung beans showed a significant positive correlation (P < 0.05) with GABA content and increment following HRH treatment, which suggested that mung beans enriched in these free amino acids might accumulate higher amounts of GABA after HRH treatment and be useful for industrial applications.     

基于贝叶斯MCMC方法的高斯烟羽模型不确定性分析

适当的大气扩散模型对于核电厂假想事故的后果评价是必要的,对其进行参数不确定性分析对于提高模型预测的可信度具有重要的意义。相比于传统的不确定性分析方法,贝叶斯方法充分考虑了已有的观测数据,马尔科夫链蒙特卡罗方法(Markov Chain Monte Carlo,MCMC)可以方便地将贝叶斯方法和高斯烟羽模型相结合。首先使用一次改变一个变量值的方法分析模型对几个重要参数的敏感性,然后选择敏感性最大的两个参数使用贝叶斯MCMC方法进行了不确定性分析。通过分析MCMC样本序列,得到了观测值的最优拟合及模拟结果的置信区间。贝叶斯方法能获得更可靠的置信区间,从而为事故后应急响应提供更好的参考数据。     

5G光模块技术及方案对比

论述了5G光模块的技术和产业化发展现状,分析了4种波分复用技术应用于5G前传网络的优缺点,给出了后续5G光模块发展的策略建议.     

磁絮凝强化技术处理厌氧消化污泥脱水液

为满足后续生物处理单元对固体悬浮物（SS）和铁浓度的进水要求，采用磁絮凝强化技术对厌氧消化污泥脱水液进行预处理。通过正交试验和单因素试验，本文考察了混凝水力条件、聚合氯化铝（PAC）投加量、聚丙烯酰胺（PAM）投加量、磁粉投加量及药剂投加顺序对磁絮凝效果的影响。试验结果表明：磁絮凝强化技术在快搅300r/min（2min）、慢搅100r/min（15min）、静置10min时，依次投加磁粉（40mg/L）、PAC（30mg/L）、PAM（4mg/L）时处理效果最好。在此运行条件下，SS和Fe³⁺去除率分别为97.61%、98.24%、絮凝指数（FI值）取得最大值、zeta电位绝对值最小，絮凝效果最佳。与对照相比，磁絮凝强化技术对SS和Fe³⁺去除率分别可提高3.70%和10.82%，同时絮体最大沉降速度可提高33%。磁絮凝技术处理后的出水不仅可以满足后续生物处理单元对SS和铁浓度的要求，还可以有效提高磁絮凝体的沉降速度，减小沉淀时间，具有较好的实用价值。     

钻削GH4169高温合金薄壁件钻削力仿真研究

GH4169高温合金的薄壁钻孔与厚壁钻孔相比有特殊性,运用ABAQUS软件进行钻削GH4169高温合金薄壁件的仿真,研究钻削加工过程中钻削参数和工件厚度对钻削力的影响规律及变化特征,分析应力的分布规律。结果表明:钻削初期,横刃的挤压和主切削刃切削长度的增加使钻削力和扭矩增大;稳定钻削阶段,横刃切出后,主切削刃切削长度不变切削直径增加,钻削力和扭矩稳定增加;钻削后期,副切削刃参与切削,主切削刃切削长度减小,轴向钻削力和扭矩减小,但副刃与孔壁的挤压摩擦,曲线波动较大;钻削速度、进给量及工件厚度的增加都会导致轴向钻削力和扭矩的增加;钻削时的最大应力分布在横刃和主切削刃与工件的接触部位。     

SAM智能综采技术在龙滩煤矿的应用

介绍了四川省首个智能综采设备在龙滩煤矿3124S工作面的应用情况,总结了SAM智能化综采的六大核心技术,包括成套设备一键启停、液压支架自动跟机、采煤机记忆割煤、机巷远程集中控制、工作环境智能监控、工况监测及故障诊断。通过现场应用,一键启停功能成功率超过90%、自动跟机率平均88%、记忆割煤使用率62%,实现了工作面设备集中控制、回采参数实时监控及故障诊断。结果表明,相较于传统综采工作面,智能化综采工作面生产人员减少50%,工效提高63%,单产提高65%。     

一种考虑风电渗透率变化的AGC方法

新能源发电渗透率的提高给传统自动发电控制（automatic generation control，AGC）带来了新的挑战。数据研究表明，风电渗透率的改变会对AGC系统的参数产生影响，在此基础，提出一种基于系统补偿的AGC方法，在AGC参数不能及时在线整定的情况下，能降低对系统稳定性的影响。首先，构建含有风电的区域互联AGC系统模型；然后，讨论了当风电渗透率发生变化时，AGC系统参数的调整依据；在此基础上，设计补偿环节与传统模型预测控制器（model predictive controller，MPC）形成串联结构，以消除当风电渗透率发生变化时，由于参数不匹配对AGC效果的不利影响；最后，通过仿真验证了所提方法的可行性和有效性，仿真结果表明：当风电渗透率发生变化时，通过补偿环节参数的调整能够有效消除其对系统参数的影响，从而获取更好的频率控制效果。     

Influence of force load on the stability of ultrasonic longitudinal–torsional composite drilling system

This study aimed to investigate the problems of system detuning, amplitude attenuation, and even vibration stop after the load was applied to the acoustic system during ultrasonic-assisted vibration processing. In the theoretical part, the overall theoretical model of the ultrasonic longitudinal–torsional composite drilling system (ULTCDS), including the longitudinal–torsional composite horn, transducer, and load was established based on the four-terminal network, combined with the longitudinal and torsional vibration equations of the variable cross-section rod. Also, the influence of the load on the input impedance and output amplitude of the acoustic system was preliminarily analyzed. In the simulation part, the static and dynamic drilling force was simulated by the pre-stressed modal and transient dynamic analyses, and the influence of the force load on the resonant frequency and output amplitude of the system was further explored. In the experiment part, the static force loading test and the ultrasonic drilling test of titanium alloy were designed. The micro-morphology of drilling holes under different processing parameters was observed, and the influence of force load on the system characteristics and stability was explored. The results showed that when the system was subjected to a force load greater than 400 N, the system current and frequency were greatly offset, the electromechanical conversion efficiency reduced, and the amplitude was attenuated to below the amplitude at empty load. In the ultrasonic-assisted drilling of titanium alloy processing, the acoustic system undergoes an obvious detuning phenomenon and the drilling quality is attenuated when the current increased by more than 60% and the frequency changed by more than 350 Hz, affecting the stability of the system and the ultrasonic-assisted processing effect.     

川北某黑色页岩型铼矿工艺矿物学研究

通过矿相显微镜、扫描电镜、电子探针、X射线能谱元素面分析等多种手段综合研究了川北某黑色页岩型铼矿中铼的赋存状态。样品为黑色页岩,有机碳含量较高。粘土矿物总量为14.6%,黄铁矿含量16.2%,石英含量37.7%。样品具典型的粘土结构,矿物粒度微细。铼有两种赋存状态,一种呈类质同象形式赋存于黄铁矿内,另一种则以分散形式存在。典型黄铁矿测点Re平均含量为0.024%。黄铁矿是Re的重要载体矿物。建议通过浮选分离黄铁矿,从而实现Re的富集。